# virsh domifaddr vm
Name MAC address Protocol Address
-------------------------------------------------------------------------------
vnet0 52:54:00:6f:dc:90 ipv4 192.168.122.84/24
# virsh dumpxml --inactive vm
...
<interface type="network">
<mac address="52:54:00:6f:dc:90">
<source network="default"></source>
<model type="virtio">
<address bus="0x00" domain="0x0000" function="0x0" slot="0x03" type="pci">
</address>
...
What you can do instead is use the NSS module libvirt-nss.
If you want to easily ssh into the guest using its libvirt name, set
# /etc/nsswitch.conf: hosts: files libvirt_guest dnsand make sure to have the correct sshd configuration in your guest.